Spherand-type hexahomotriazacalix[6]arenes were synthesized from the cyclization reactions of bis(chloromethyl)biphenol and primary amines in moderate yields. The ¹H-NMR and CD spectra of the spherand-type chiral homoazacalixarenes indicated that the chiral transmission from the point chirality of the chiral amine moieties to the axial chirality of the biphenol units.