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Current Topics in Phytochemistry   Volumes    Volume 17 
Abstract
Determination of absolute configuration of the most abundant garlic sulfide, garlicnin B1
Toshihiro Nohara, Mona El-Aasr, Tsuyoshi Ikeda, Shang-Hui Gao, Kazumi Yokomizo
Pages: 55 - 61
Number of pages: 7
Current Topics in Phytochemistry
Volume 17 

Copyright © 2021 Research Trends. All rights reserved

ABSTRACT
 
As part of our continuing studies on the Allium sulfides exhibiting antitumor effects, we identified several sulfides termed garlicnins and characterized their structures. They were classified into acyclic-, 3,4-dimethylthiolane-, 2-methylthiolane-, 1,2-dithiolane-, 2-oxothiolane-, and bis-thiolane-type sulfides. However, it was pointed out that some parts of 3,4-dimethylthiolane-type had structural inaccuracies. Therefore, we corrected them and determined the absolute configuration of the major sulfide, garlicnin B1, which is also the most abundant Allium sulfide and expected to possess antitumor effect.  
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