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Trends in Organometallic Chemistry   Volumes    Volume 4 
Abstract
Metal-assisted functionalization of diphosphines
Casimiro Rodriguez, Jose M. Vila, Alberto A. Fernandez, Jesus J. Fernandez, Margarita Lopez Torres, Roberto Mosteiro
Pages: 99 - 107
Number of pages: 9
Trends in Organometallic Chemistry
Volume 4 

Copyright © 2002 Research Trends. All rights reserved

ABSTRACT

The tertiary diphosphines Ph2PCH2PPh2, bis(diphenylphosphino)methane (dppm) and (Ph2P)2C=CH2, 1,1-bis(diphenylphosphino)ethane (vdpp), may be functionalized when bonded to the metal atom in coordination and organometallic complexes. In the former case, the acidity of the CH2 group is enhanced, and in the latter the C=C double bond is activated towards nucleophilic addition.

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