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Trends in Photochemistry & Photobiology   Volumes    Volume 3  Issue 1
Abstract
Imino sulfonates as photoacid generators: Photochemistry and applications
Masamitsu Shirai, Masahiro Tsunooka
Pages: 351 - 359
Number of pages: 9
Trends in Photochemistry & Photobiology
Volume 3  Issue 1

Copyright © 1994 Research Trends. All rights reserved

ABSTRACT
 
Imino sulfonate compounds which can form sulfonic acids upon UV irradiation were synthesized and the mechanism for the photolysis was evaluated. Imino sulfonates are non-ionin photoacid generators and they are soluble in common organic solvents. The photoinduced crosslinking of poly(glycidyl methacrylate) (PGMA) using imino sulfonates was studied. The photoinduced acid-catalyzed thermal removal of tert-butoxycarbonyl (t-BOC) units in poly(4-tert-butoxycarbonyloxystyrene) (PBOS) in film was also studied.
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